Branched quaternary ammonium amphiphiles: nematic ionic liquid crystals near room temperature.

نویسندگان

  • Wen Li
  • Jing Zhang
  • Bao Li
  • Mingliang Zhang
  • Lixin Wu
چکیده

Branched quaternary ammonium molecules were synthesized and characterized by calorimetric, optical and X-ray diffraction studies; two of the molecules exhibited interesting nematic liquid crystalline behavior close to room temperature.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Unexpected role of linker position on ammonium gemini surfactant lyotropic gyroid phase stability.

Arising from the water-driven self-assembly of amphiphiles over generally narrow temperature and composition phase windows, aqueous lyotropic liquid crystal (LLC) network phases are useful in applications as therapeutic delivery vehicles and templates for mesoporous material syntheses. While a clear set of amphiphile design rules that enables access to these intricate three-dimensional structur...

متن کامل

Investigation into the temperature dependence of isotropic- nematic phase transition of Gay- Berne liquid crystals

Density functional approach was used to study the isotropic- nematic (I-N) transition and calculate the values of freezing parameters of the Gay- Berne liquid crystal model. New direct and pair correlation functions of a molecular fluid with Gay- Berne pair potential were used. These new functions were used in density functional theory as input to calculate the isotropic- nematic transition den...

متن کامل

One-pot synthesis of 2,4,5-trisubstituted imidazoles catalyzed by dicationic magnetic room temperature ionic liquid

Regarding the green chemistry's goals, dicationic magnetic room temperature ionic liquid open up new avenue to introduce an amazing and efficient system for facilitating catalyst recovery in different organic reactions. Ability of this dicationic magnetic room temperature ionic liquid catalyst in the one-pot three-components condensation reaction of benzil, aromatic aldehyde, and ammonium aceta...

متن کامل

Lyotropic liquid crystalline phase behaviour in amphiphile-protic ionic liquid systems.

Approximate partial phase diagrams for nine amphiphile-protic ionic liquid (PIL) systems have been determined by synchrotron source small angle X-ray scattering, differential scanning calorimetry and cross polarised optical microscopy. The binary phase diagrams of some common cationic (hexadecyltrimethyl ammonium chloride, CTAC, and hexadecylpyridinium bromide, HDPB) and nonionic (polyoxyethyle...

متن کامل

Aqueous gelation of ionic liquids: reverse thermoresponsive ion gels.

The aqueous gelation of a quaternary ammonium oligo(propylene oxide)-based ionic liquid yields ion gels with a reverse thermoresponsive behavior (i.e., mechanical moduli and viscosity increase with temperature) and enhanced ionic conductivities.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 35  شماره 

صفحات  -

تاریخ انتشار 2009